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New organoselenium(II) derivatives containing Se-antimony bonds

M. KULCSAR1, M. BOANCA1, A. SILVESTRU1,* , H. J. BREUNIG2

Affiliation

  1. Faculty of Chemistry & Chemical Engineering, “Babes-Bolyai” University, RO-400028, Cluj-Napoca, Romania
  2. Institut für Anorganische und Physikalische Chemie, Universität Bremen, D-28534 Bremen, Germany

Abstract

New organoantimony(III) selenolates, RSb[Se{C6H4(CH2NMe2)-2}]2 [R = (Me3Si)2CH (1), Me3CCH2 (2), Ph (3)] were prepared and characterized by mass spectrometry and NMR (1H, 13C) NMR spectroscopy. On the basis of the NMR data, a structure with nitrogen atoms of the pending arms coordinated to the metal centre was proposed..

Keywords

Organo-selenium derivatives, Se-Sb bonds.

Submitted at: Nov. 15, 2006
Accepted at: March 15, 2007

Citation

M. KULCSAR, M. BOANCA, A. SILVESTRU, H. J. BREUNIG, New organoselenium(II) derivatives containing Se-antimony bonds, Journal of Optoelectronics and Advanced Materials Vol. 9, Iss. 3, pp. 725-728 (2007)