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Preparation of 6-diallylamino-1,3,5-triazine2,4-dithiol functional nanofilm by cyclic voltammetry on aluminum surface

FANG WANG1,* , YABIN WANG1, YANNI LI1

Affiliation

  1. College of Science, Northwest Agriculture & Forest University, No.22, XiNong Road, Shannxi-Yangling, 712100, China

Abstract

The functional polymeric nanofilm of 6-diallylamino-1,3,5-triazine-2,4-dithiol monosodium (DAN) was successfully prepared by cyclic voltammetry method in NaNO2 supporting electrolyte on pure aluminum surface. Based on results of cyclic voltammetry and X-ray photoelectron spectroscopy (XPS), the mechanism of electrochemical polymerization was proposed, which indicated that radical polymerization took place during the electrochemical polymerization process. The obtained poly(6-diallylamino-1,3,5-triazine-2,4-dithiol) (PDA) functional nanofilm was also investigated by means of FT-IR spectra. The experimental results also showed that the structure of polymeric nanofilm was consisted of Al2O3 and PDA. It is expected that this technique will bring the direct joining between aluminum and rubber in the process of curing with the formed polymeric nanofilm..

Keywords

triazinedithiol monosodium; aluminum; functional polymeric nanofilm; electropolymerization.

Submitted at: Nov. 1, 2010
Accepted at: Nov. 25, 2010

Citation

FANG WANG, YABIN WANG, YANNI LI, Preparation of 6-diallylamino-1,3,5-triazine2,4-dithiol functional nanofilm by cyclic voltammetry on aluminum surface, Journal of Optoelectronics and Advanced Materials Vol. 12, Iss. 12, pp. 2449-2455 (2010)