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Spectroscopic investigation of some aromatic azides

A. AIRINEI1,* , E. RUSU1, V. BARBOIU1, D. TIMPU1

Affiliation

  1. “Petru Poni” Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda, 41A, 700487-Iasi, Romania

Abstract

The electronic absorption spectra of some aromatic azides based on 4,4’-diaminobiphenyl or 4,4’- diaminobenzophenone, etc. Were discussed in terms of the primary products and the mechanism of photolysis reactions of azides. The progress of the photochemical reactions was monitored by means of the optical absorption spectra. It was found that the photolysis of biphenyl azide in solution develops the first-order kinetics model. Thin azoaromatic polymer films were obtained by the photolysis of aromatic azides in vacuum..

Keywords

Aromaric azides, Electronic absorption spectra, Potolysis, Azoaromatic conjugated polymers.

Submitted at: Nov. 2, 2006
Accepted at: April 15, 2007

Citation

A. AIRINEI, E. RUSU, V. BARBOIU, D. TIMPU, Spectroscopic investigation of some aromatic azides, Journal of Optoelectronics and Advanced Materials Vol. 9, Iss. 4, pp. 1029-1032 (2007)