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Synthesis, spectroscopic and nonlinear characterization of 1,1ʹ-(Ethylene-1,2-diyl)dipyridinium dichlorodinitratocuprate(II)

M. D. ZIDAN1,* , M. M. AL-KTAIFANI1, M. S. EL-DAHER2, A. ALLAHHAM1, A. GHANEM2, A. AL SHARIF1

Affiliation

  1. Atomic Energy Commission, P. O. Box 6091, Damascus, Syria
  2. Higher Institute for Laser Research and Applications, Damascus University, Syria

Abstract

The new organic-inorganic hybrid salt: 1,1ʹ-(Ethylene-1,2-diyl)dipyridinium dichlorodinitratocuprate(II) was synthesized and characterized using UV-Vis, FTIR and NMR techniques. The nonlinear optical properties and optical switching were investi-gated using z-scan technique with CW laser beams at λ=532 and 635 nm. Theoretical fitting was performed to the recorded experimental data to calculate the nonlinear optical parameters including the thermo-optic coefficient calculations. The results have confirmed that the studied sample exhibited revers saturation absorption processes. The thermal lens effect was demonstrated all optical switching for the new organic-inorganic hybrid salt. The reported results led to possible potential ap-plications of the studied complex in future promising optoelectronic applications..

Keywords

Cross phase modulation, Organic-inorganic hybrid salt, Nonlinear coefficients.

Submitted at: Oct. 10, 2019
Accepted at: Feb. 15, 2021

Citation

M. D. ZIDAN, M. M. AL-KTAIFANI, M. S. EL-DAHER, A. ALLAHHAM, A. GHANEM, A. AL SHARIF, Synthesis, spectroscopic and nonlinear characterization of 1,1ʹ-(Ethylene-1,2-diyl)dipyridinium dichlorodinitratocuprate(II), Journal of Optoelectronics and Advanced Materials Vol. 23, Iss. 1-2, pp. 22-28 (2021)